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电子吸收的光谱学

电子吸收的光谱学

作者:J-R Lalanne  著

出版社:东南大学出版社

出版时间:1999-12-01

ISBN:9789810238612

定价:¥451.00

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内容简介
  This book, a companion volume to Electronic Structure and Chemical Bonding (World Scientific, 1996), is concerned with the teaching of optical spectroscopies of electronic absorption. It is the culmination of about ten years of experience in the teaching of the subject and the training of students to become teachers in the physical sciences. The book covers topics of current research and includes about 30 problems with solutions, most of which are adapted from tests proposed recently at the "Aggregation" in chemistry and physics. It provides as much coverage of elementary quantum mechanics, group theory and the electronic structure of molecules as is necessary for the reader to understand the rest of the topics. Also included are numerous appendices, often presented as charts to facilitate assimilation, as well as short bibliographies, limited to basic books and review articles. This volume will be an invaluable guide for teachers and potential teachers in the physical sciences, and more generally for students and engineers in chemical physics and physics.
作者简介
暂缺《电子吸收的光谱学》作者简介
目录
Preface
Acknowledgments
Symbols
PART I Theoretical Frame
Chapter I.- Introduction
Chapter II. - Classical Theory of Light
II. 1. Introduction: The different representations of light
II.2. Classical theory of light
  II.2.1. Electromagnetism and Maxwell's equations
   II.2.1.1. Maxwell's equations
   II.2.1.2. The wave equation
  II.2.2. Three solutions for Maxwell's equations
   II.2.2.1. The spherical wave
   II.2.2.2. The plane wave
   II.2.2.3. Gaussian wave
 II.3. Exercises and problems
  II. 3.1. Electromagnetic wave propagation in vacuum
  II.3.2. Search for a particular Gaussian solution of the wave equation
  II.3.3. Treatment of Gaussian wm,es with lenses
 II.4. Appendices
  II.4.1. Table of electromagnetic waves
  II. 4.2. Various forms of the Maxwell's equations
  ]1.4.3. Three particular solutions to the wave equation
 II.5. Bibliography
Chapter HI- Matter and its properties
 III. 1. Non relativistic quantum mechanics
  III.1.1. Fundamental principles and brief history
   III. 1.1.1. Probabilistic description
   III. 1.1.2. The problem of measurement and operators
  III.1.2. Principles of the non relativistic quantum theory
   III.l.2.1. Postulates concerning the description of the system
    III. 1.2.2. Principles for the measurement of physical quantities
    III. 1.2.3. Evolution principle
    III.1.2.4. Correspondence principle
    III.1.2.5. Spin creation principle
    III. 1.2.6. Antisymmetrization principle
 III.2. Symmetry and group theory
   III. 2.1. Symmetry elements and svmmsetry operations
   III.2.2. Representation of an operation by an operator
   III.2.3. Group structure and classification
   III.2.4. Group representation
    III.2.4.1. Introduction to the notion of representation
    III.2.4.2. Representation properties
    III.2.4.3. Direct product of two representations
 III.3. Application of quantum mechanics and group theory to the description of stationary electronic states in atoms and molecules
   III.3.1. Description of the electronic structure of the hydrogen atom and of the hydrogenic atoms
    III. 3.1.1. Solution of tile eigenvalue equation for tile Hamiltonian operator
    IlI.3.1.2, Energy and shell model
    III.3.1.3. State vector and atomic orbital multiplicity
    III.3.1.4. Various representations of probability densities in real space
    III.3.1.5. Spin orbit coupling
   III.3.2. The description of the electronic structure of many-electron atoms
   III.3.2.1. Central field approximation
III.3.2.2. Electrostatic and magnetic interactions: Russel-Saunders and spin-orbit couplings
III.3.2.3. Description of configurations
    III.3.3.Description of electronic structure of molecules
    III.3.3.1. General presentation
    Ill.3.3.2. Methods for solving the electronic eigenvalue equation
   III.3.4. Vibrational and rotational structure of electronic levels in atoms and molecules
    IlI.3.4.1. Vibrational structure
    III.3.4.2. Rotational structure
    III.3.4.3. Vibration-rotation interaction
  III.3.5. Conclusions and consequences about electronic levels
 IlI.4. Exercises et problems
  III.4.1. Questions about symmetry: true or false?
  III.4.2. General aspects of LCAO theory
  III.4.3. Study of the orbitals of 1, 3 butadiene
  III.4.4. Energy ofsinglet and triplet states of a two-electron system
 III.5. Appendices
  III.5.1. Main properties of linear transformations and matrices
  III.5.2. Representation of an operator by a matrix
  III.5.3. Tables of the postulates of quantum theory
  III.5. 4. Tables of characters of the symmetry groups used in this book
 III.6. Bibliography
……
PART II Optical Spectroscopies of Electronec Absorption
INDEX
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