电子吸收的光谱学

　　This book， a companion volume to Electronic Structure and Chemical Bonding （World Scientific， 1996）， is concerned with the teaching of optical spectroscopies of electronic absorption. It is the culmination of about ten years of experience in the teaching of the subject and the training of students to become teachers in the physical sciences.　The book covers topics of current research and includes about 30 problems with solutions， most of which are adapted from tests proposed recently at the "Aggregation" in chemistry and physics. It provides as much coverage of elementary quantum mechanics， group theory and the electronic structure of molecules as is necessary for the reader to understand the rest of the topics. Also included are numerous appendices， often presented as charts to facilitate assimilation， as well as short bibliographies， limited to basic books and review articles.　This volume will be an invaluable guide for teachers and potential teachers in the physical sciences， and more generally for students and engineers in chemical physics and physics.

暂缺《电子吸收的光谱学》作者简介

Preface
Acknowledgments
Symbols
PART I Theoretical Frame
Chapter I.- Introduction
Chapter II. - Classical Theory of Light
II. 1. Introduction: The different representations of light
II.2. Classical theory of light
　　II.2.1. Electromagnetism and Maxwell's equations
　　　II.2.1.1. Maxwell's equations
　　　II.2.1.2. The wave equation
　　II.2.2. Three solutions for Maxwell's equations
　　　II.2.2.1. The spherical wave
　　　II.2.2.2. The plane wave
　　　II.2.2.3. Gaussian wave
　II.3. Exercises and problems
　　II. 3.1. Electromagnetic wave propagation in vacuum
　　II.3.2. Search for a particular Gaussian solution of the wave equation
　　II.3.3. Treatment of Gaussian wm,es with lenses
　II.4. Appendices
　　II.4.1. Table of electromagnetic waves
　　II. 4.2. Various forms of the Maxwell's equations
　　]1.4.3. Three particular solutions to the wave equation
　II.5. Bibliography
Chapter HI- Matter and its properties
　III. 1. Non relativistic quantum mechanics
　　III.1.1. Fundamental principles and brief history
　　　III. 1.1.1. Probabilistic description
　　　III. 1.1.2. The problem of measurement and operators
　　III.1.2. Principles of the non relativistic quantum theory
　　　III.l.2.1. Postulates concerning the description of the system
　　　 III. 1.2.2. Principles for the measurement of physical quantities
　　　 III. 1.2.3. Evolution principle
　　　 III.1.2.4. Correspondence principle
　　　 III.1.2.5. Spin creation principle
　　　 III. 1.2.6. Antisymmetrization principle
　III.2. Symmetry and group theory
　　 III. 2.1. Symmetry elements and svmmsetry operations
　　 III.2.2. Representation of an operation by an operator
　　 III.2.3. Group structure and classification
　　 III.2.4. Group representation
　　　 III.2.4.1. Introduction to the notion of representation
　　　 III.2.4.2. Representation properties
　　　 III.2.4.3. Direct product of two representations
　III.3. Application of quantum mechanics and group theory to the description of stationary electronic states in atoms and molecules
　　 III.3.1. Description of the electronic structure of the hydrogen atom and of the　hydrogenic atoms
　　　 III. 3.1.1. Solution of tile eigenvalue equation for tile Hamiltonian operator
　　　 IlI.3.1.2, Energy and shell model
　　　 III.3.1.3. State vector and atomic orbital multiplicity
　　　 III.3.1.4. Various representations of probability densities in real space
　　　 III.3.1.5. Spin orbit coupling
　　 III.3.2. The description of the electronic structure of many-electron atoms
　　 III.3.2.1. Central field approximation
III.3.2.2. Electrostatic and magnetic interactions: Russel-Saunders and spin-orbit couplings
III.3.2.3. Description of configurations
　　　　III.3.3.Description of electronic structure of molecules
　　　　III.3.3.1. General presentation
　　　　Ill.3.3.2. Methods for solving the electronic eigenvalue equation
　　 III.3.4. Vibrational and rotational structure of electronic levels in atoms　and molecules
　　　 IlI.3.4.1. Vibrational structure
　　　 III.3.4.2. Rotational structure
　　　 III.3.4.3. Vibration-rotation interaction
　　III.3.5. Conclusions and consequences about electronic levels
　IlI.4. Exercises et problems
　　III.4.1. Questions about symmetry: true or false?
　　III.4.2. General aspects of LCAO theory
　　III.4.3. Study of the orbitals of 1, 3 butadiene
　　III.4.4. Energy ofsinglet and triplet states of a two-electron system
　III.5. Appendices
　　III.5.1. Main properties of linear transformations and matrices
　　III.5.2. Representation of an operator by a matrix
　　III.5.3. Tables of the postulates of quantum theory
　　III.5. 4. Tables of characters of the symmetry groups used in this book
　III.6. Bibliography
……
PART II Optical Spectroscopies of Electronec Absorption
INDEX