高分子物理学中的标度概念（影印版）

　　The physics of long flexible chains was pioneered by several great scientists： Debye， Kuhn， Kramers， Flory， and so forth. They constructed the basic ideas; those concerning static properties are summarized in Flory's book， and those concerning dynamics in various reviews. More recently， a second stage in the physics of polymers has evolved， because of the availability of new experimental and theoretical tools. As usual， these new techniques brought about some important changes in our viewpoints. ...

暂缺《高分子物理学中的标度概念（影印版）》作者简介

Preface.
Introduction:LongFlexibleChains
PartASTATICCONFORMATIONS
IASingleChain
I.1.TheNotionofanIdealChain
I.1.1.Simplerandomwalks
I.1.2.Moregeneralmodelsforidealchains
I.1.3.Idealchainsunderexternalactions
I.1.4.Paircorrelationsinsideanidealchain
I.1.5.Summary
I.2.A"Real"ChaininaGoodSolvent
I.2.1.Themainexpedments
I.2.2.Numericaldataonself-avoidingwalks
I.2.3.Correlationsinsideaswollencoil
I.2.4.Summary
I.3.TheFloryCalculationoftheExponentv
I.3.1.Principles
I.3.2.Chainsareidealabovefourdimensions
I.3.3.WhyistheFierymethodsuccessful?
I.4.ConstrainedChains
I.4.1.Achainundertraction
I.4.2.Squeezingarealchaininatube
IIPolymerMelts
II.1.MoltenChainsAreIdeal
II.1.1.Aself-consistentfieldargument
II.1.2.Screeningindensepolymersystems
II.1.3.Onelongchainamongshorterchains
II.1.4.Mixedchainsversussegregatedchains
II.1.5.Summary61
II.2.MicroscopicStudiesofCorrelationsinMelts
II.2.1.Necessityoflabeledspecies
II.2.2.Thecorrelationhole
II.2.3.Moregeneralsequences
II.2.4.Thecorrelationholeintwodimensions
II.2.5.Mixturesoflabeledandunlabeledchains
II.2.6.Summary67
IIIPolymerSolutionsinGoodSolvents
III.1.TheMeanFieldPicture(Flory-Huggins)
III.1.1.Entropyandenergyinalatticemodel
III.1.2.Lowconcentrations
III.1.3.Osmoticpressures
III.1.4.Critiqueofmeanfieldtheory
III.2.ScalingLawsforAthermalSolvents
III.2.1.Theoverlapthresholdc*
III.2.2.Thediluteregime
III.2.3.Semi-dilutesolutions
III.2.4.Thecorrelationlength
III.2.5.Thenotionofblobs
III.2.6.Correlationfunctions
III.2.7.Screeninginsemi-dilutesolutions
III.3.ConfinedPolymerSolutions
III.3.1.Asemi-dilutesolutionincontactwitharepulsivewall
III.3.2.Asemi-dilutesolutioninacylindricalpore
IVIncompatibilityandSegregation
IV.1.GeneralPrinciplesandQuestions
IV.1.1.Thetrendtowardsegregation
IV.1.2.Casesofpartialcompatibility
IV.1.3.Specificfeaturesofpolymersegregation
IV.2.Polymer-PolymerSystems
IV.2.1.ThermodynamicPrinciples
IV.2.2.Thecoexistencecurveinthesymmetricalcase
IV.2.3.Metastablestatesandthespinodalcurve
IV.2.4.Thecriticalpoint
IV.2.5.Criticalfluctuations
IV.2.6.Absenceofanomalousexponents
IV.3.PolymerPlusPoorSolvent
IV.3.1.Regionsinthephasediagram
IV.3.2.AsinglecoilnearT=O
IV.3.3.Semi-dilutesolutionsatT=e
IV.3.4.Semi-dilutesolutions:crossoverbetweengoodandpoorsolvent
IV.3.5.Vicinityofthecoexistencecurve
IV.4.PolymerPlusPolymerPlusSolvent
IV.4.1.Goodsolventandstrongsegregationfactor
IV.4.2.Goodsolventandweaksegregationfactor
IV.4.3.Thetasolvents
VPolymerGels
V.1.PreparationofGels
V.1.1.Chemicalpathways
V.1.2.Unorthodoxgelationprocesses
V.1.3.Physicalgelation
V.1.4.Stronggelationversusweakgelation
V.1.5.Relationshipbetweenpreparationandpropertiesofgels
V.2.TheSol-GelTransition
V.2.1.Theclassicalpicture
V.2.2.Gelationwithoutsolvent:thepercolationmodel
V.2.3.Largeclustersbelowthegelationthreshold
V.2.4.Gelpropertiesjustabovethreshold
V.2.5.Aquickglanceattheclassicaltheory
V.2.6.Theclassicaltheoryworksinsixdimensions
V.2.7.Thespecialcaseofvulcanization
V.2.8.Dilutioneffects:competitionbetweengelationandprecipitation
V.3.GelsinGoodSolvents
V.3.1.Thec*theorem
V.3.2.Paircorrelationsinthegel
V.3.3.Elasticityofswollengels
V.3.4.Spinodaldecomposition
V.3.5.Summary
PartBDYNAMICS
VIDynamicsofaSingleChain
VI.1.HistoricalBackground
VI.1.1.TheRousemodel
VI.1.2.Weaknessofinternalfrictioneffects
VI.1.3.Critiqueofthemodeconcept
VI.2.DynamicScalinginGoodSolvents
VI.2.1.TheKirkwoodapproximationforchainmobility
VI.2.2.Inelasticscatteringoflight
VI.2.3.Thefundamentalrelaxationtime
VI.2.4.Staticviscosityofdilutesolutions
VI.2.5.Frequencydependenceofviscosities
VI.3.SpecialFlowProblems
VI.3.1.Deformationinstrongextensionalflows
VI.3.2.Dynamicsofachaininsideacylindricalpore
VI.4.ProblemsofInternalFriction
VI.4.1.Threeformsoffriction
VI.4.2.EvidencefortheCerfterm
VI.4.3.OriginoftheCerffriction
VI.4.4.Summary..
VIIMany-ChainSystems:TheRespirationModes
VII.1.Semi-DiluteSolutions
VII.1.1.Longitudinalmodes
VII.1.2.Twodiffusioncoefficients
VII.1.3.Thesedimentationcoefficient
VII.1.5.Cooperativediffusion
VII.1.5.Summary
VII.2.DynamicsnearaCriticalPoint
VII.3.DynamicsofGels
VII.3.1.Longitudinalmodesofswollengels
VII.3.2.Slowmotionsnearthespinodalthreshold
VII.3.3Dynamicsatthescl-geltransition
VIIIEntanglementEffects
VIII.1.DynamicsofMeltsandConcentratedSolutions
VIII.1.1.Rubber-likeandliquid-likebehaviors
VIII.A.2.Elasticmodulusofthetransientnetwork
VIII.1.3.Viscosityandterminaltime
VIII.2.ReptationofaSingleChain
VIII.2.1.Coilstrappedinanetwork
VIII.2.2.Theterminaltime,τt
VIII.2.3.Translationaldiffusion
VIII.2.4.Reptationinswollensystems
VIII.2.5.Reptationofabranchedchain
VIII.3.ConjecturesonPolymerMelts
VIII.3.1.Onelongchaininameltofshorterchains
VIII.3.2.Newtonianviscositiesinahomodispersemelt
VIII.3.3.Behaviorinstrongtransverseshearflows
VIII.3.4.Criticaldynamicsinentangledbinarymixtures
VIII.3.5.Summary
PartCCALCULATIONMETHODS
IXSelf-ConsistentFieldsandRandomPhaseApproximation
IX.1.GeneralProgram
IX.2.Self-ConsistentFields
IX.2.1.Anidealchainunderexternalpotentials
IX.2.2.Situationsofgroundstatedominance
IX.2.3.Self-consistencywithgroundstatedominance
IX.3.TheRandomPhaseApproximationforDenseChains
IX.3.1.Definitionofresponsefunctions
IX.3.2.Responsefunctionsfornoninteractingchains
IX.3.3.Self-consistentcalculationofresponses
XRelationshipsbetweenPolymerStatisticsandCriticalPhenomena
X.1.BasicFeaturesofCriticalPoints
X.1.1.Largecorrelatedregions
X.1.2.Criticalexponentsforaferromagnet
X.1.3.Relations.amongexponents
X.1.4.Correlationfunctions
X.1.5.Thenvectormodel
X.2.TheSingleChainProblem
X.2.1.Thelimitn=0
X.2.2.Themagneticpartitionfunctionexpandedinself-avoidingloops
X.2.3.Spincorrelationsandtheone-chainproblem
X.2.4.Propertiesofself-avoidingwalks
X.3.ManyChainsinaGoodSolvent
X.3.1.ThedesCloiseauxtrick
X.3.2.OverlapconcentrationΦ*andrelatedscalinglaws
X.3.3.Crossoverbetweendiluteandsemi-dilutesolutions
X.3.4.Correlationsinthesolution
X.3.5.Currentextensions
X.3.6.Whatistheorderparameter?
XIAnIntroductiontoRenormalizationGroupIdeas
XI.1.DecimationalongtheChemicalSequence
XI.1.1.Asinglechaininagoodsolvent
XI.1.2.Groupingthemonomersintosubunits
XI.1.3.Iteratingtheprocess
XI.1.4.Existenceofafixedpoint
XI.1.5.Scalinglawforthechainsize
XI.1.6.Freeenergyofasinglechain
XI.1.7.Calculationsnearfourdimensions
XI.2.Applications
XI.2.1.Polyelectrolytes
XI.2.2.Collapseofasinglechain
XI.2.3.Semi-dilutesolutionsandblobs
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