表面等离激元增强分子光谱

　　本书内容被分为六章，内容上主要是分子能谱的原理和应用，原理包含物理机制和检测方法，多用示意图来解释相关物理过程，方便理解，使读者对于分子光谱的分类及类型之间的区别有初步的了解，利用本书介绍的分析方法，可以对实验和理论计算得到的拉曼光谱进行合理分析和解释。应用部分聚焦科技前沿，着重讨论近几年国内外的发展成果，引用文献资料更新颖。使读者对于分子光谱的分类及类型之间的区别有初步的了解，利用本书介绍的分析方法，可以对实验和理论计算得到的拉曼光谱进行合理分析和解释。

　　孙萌涛，北京科技大学数理学院教授，博士生导师。中国科学院大连化学物理研究所博士，师从沙国河院士；瑞典隆德大学博士后；先后就职于瑞典隆德大学，中国科学院物理研究所。自主研发了高真空针尖增强拉曼光谱仪，实现了目标分子拉曼光谱的超灵敏检测，并揭示了表面等离激元增强拉曼光谱的物理和化学机制。截至目前，已在Light： Science & Applications、Advance Materials、Small 等期刊上发表高水平论文150余篇，包含8篇ESI高被引论文，论文已被引用5600余次，单篇引用z高230次，H因子40。主持国家自然科学基金重大研究计划2项；国家自然科学基金面上项目2项；科技部重大研究计划1项 。

CONTENTS



Chapter 1Introduction

References

Chapter 2Molecular Spectroscopy

2.1Ultravioletvisible (UVvis) Absorption Spectroscopy

2.1.1Principles and characteristics of
UVvis absorption spectroscopy

2.1.2Detection and application of UVvis
absorption spectroscopy

2.1.3Introduction to onephoton absorption

2.1.4Introduction to twophoton absorption (TPA)

2.2Fluorescence Spectrum

2.2.1Principle and classification of fluorescence spectrum

2.2.2Detection and application of fluorescence spectroscopy

2.3Vibrational Spectroscopy

2.3.1Vibration modes

2.3.2IR spectrum

2.3.3Raman spectroscopy

2.3.4Relationship between Raman spectrum
and IR spectrum

2.4Rotational Spectroscopy

References

Chapter 3Physical Principles of Surface Plasmon

3.1Excitation of Surface Plasmon

3.2Propagation of Surface Plasmon

3.3Application of Surface Plasmon

References

Chapter 4Surface PlasmonEnhanced Absorption and
Fluorescence Spectroscopy

4.1SurfacePlasmoEnhanced Absorption Spectroscopy

4.2SurfacePlasmonEnhanced Fluorescence Spectroscopy

4.2.1Introduction to surfaceplasmonenhanced fluorescence

4.2.2Application of plasmonenhanced fluorescence

4.3SurfacePlasmonEnhanced Resonance Fluorescence
Energy Transfer

References

Chapter 5SurfacePlasmonEnhanced Molecular Vibration Spectroscopy

5.1The Connection between Raman Spectroscopy and SERS

5.2SurfacePlasmonEnhanced Raman Spectroscopy

5.2.1Principles of plasmonenhanced Raman spectroscopy

5.2.2Applications of surfaceplasmonenhanced
Raman spectroscopy

References

Chapter 6SurfacePlasmonEnhanced Molecular IR Vibration Spectroscopy

6.1Principles of IR Vibration Spectroscopy

6.2SurfacePlasmonEnhanced IR Vibration Spectroscopy

6.2.1Principles of surfaceplasmonenhanced
IR vibration spectroscopy

6.2.2Applications of surfaceplasmonenhanced
IR vibration spectroscopy

References