书籍详情
Metal-Promoted Organic Reactions
作者：Ming Zhang 著
出版社：化学工业出版社
出版时间：2014-12-01
ISBN：9787122224453
定价：¥128.00
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内容简介
《Metal-Promoted Organic Reactions》重点介绍金属促进的有机化学反应，全书由八部分组成，内容包括过渡金属催化的通过SP2C-H官能化合成杂环化合物、过渡金属催化的通过SP3C-H官能化合成杂环化合物、铜催化的芳烃C-H官能化、芳烃C-H转化为C-N键、唑类化合物的胺化、杂环化合物不对称官能化、烯烃醛酮和酰胺氢硅化、茂钛族络合物的合成及催化烯烃氢化等，对反应机理进行了详细介绍。反映了相关领域的现状并进行了展望。
《Metal-Promoted Organic Reactions》可供从事有机化学、药物化学的科研人员参考，也可作为高等院校高年级本科生及研究生的教学参考书。
《Metal-Promoted Organic Reactions》可供从事有机化学、药物化学的科研人员参考，也可作为高等院校高年级本科生及研究生的教学参考书。
作者简介
章明，江西师范大学化学化工学院，副教授，章明，男，副教授，江西师范大学化学化工学院教师，1992年从华东师范大学研究生毕业后，一直从事有机化学的教学与科研工作，2005年获得副教授资格。一直从事与有机化学相关的科研工作，包括从天然药物中分离有效成分、合成偶氮化合物并研究它们与金属的显色反应、合成抗生素和医药中间体、合成茂金属配位化合物并利用它们催化氢化烯烃、有机合成方法学等。2003年后我开始关注有机合成方法学，在这方面做了一些科研，利用饱和碳-氢键活化合成了一系列异吲哚酮，这个工作发表在Heterocycles上，Ming Zhang,* Tianbao Chen, and Qinhua Liu，ISOINDOLONE SYNTHESIS VIA INTRAMOLECULAR COUPLING OF BENZYLIC C-H BONDS WITH AMIDE N-H BONDS. HETEROCYCLES 2014, 89,1255. 论文发表后立即受到国际同行的好评，Prof. Victor Snieckus from Queen’ s University, Canada 挑选该篇论文为 Highlights in Current Synthetic Organic Chemistry (当代合成有机化学的亮点)，见: Synfacts 2014, 10(6), 0571. 受邀为Advanced Synthesis ＆ Catalysis，Organometallics，Journal of Organometallic Chemistry，Current Organic Chemistry, Tetrahedron Letters，Synthetic Communications等杂志审稿。目前发表SCI收录的论文22篇以上。
在国外专业期刊发表多篇关于有机合成方法学的综述，其中在Advanced Synthesis & Catalysis（ADVANCED SYNTHESIS & CATALYSIS ，2009,351,2243-2270）发表的论文被引用83次。
目前正在主持的国家自然科学基金项目一项（No. 21262017 ）。
在国外专业期刊发表多篇关于有机合成方法学的综述，其中在Advanced Synthesis & Catalysis（ADVANCED SYNTHESIS & CATALYSIS ，2009,351,2243-2270）发表的论文被引用83次。
目前正在主持的国家自然科学基金项目一项（No. 21262017 ）。
目录
1 Heterocycle Synthesis through Direct Coupling of Aromatic and Vinylic C-H Bonds
1.1 Introduction
1.2 Construction of carbazoles
1.2.1 Tandem C H functionalization and C N bond formation
1.2.2 Pd （OAc）2 catalyzed oxidative biaryl synthesis
1.3 Construction of benzoxazoles
1.4 Construction of benzimidazoles
1.5 Construction of 2 substituted benzothiazoles
1.6 Construction of 3 aryl/alkylindazoles
1.7 Construction of indoles
1.8 Construction of indole derivatives oxindoles and indolines
1.8.1 Construction of oxindoles
1.8.2 Construction of indolines
1.9 Construction of benzolactams and phthalimides
1.10 Construction of dibenzofurans
1.11 Construction of brigehead unsaturated bicyclic enamines
1.12 Conclusion
References
2 Heterocycle Synthesis through Direct Coupling of Saturated C-H Bonds
2.1 Introduction
2.2 Intramolecular cyclization
2.2.1 C C bond formation
2.2.2 C N bond formation
2.2.3 C O bond formation
2.3 Intermolecular cyclization
2.3.1 Cyclization with insertion of alkenes
2.3.2 Cyclization with insertion of CO
2.3.3 Cyclization with insertion of alkynes
2.4 Conclusions
References
3 Direct Coupling of Aromatic C-H Bonds with a Nitrogen Atom
3.1 Introduction
3.2 C N bond formation of arenes having directing groups
3.2.1 Copper catalyzed/mediated C N bond formation
3.2.2 Palladium catalyzed C N bond formation
3.3 Copper（Ⅱ） acetate catalyzed/mediated C N bond formation of polyfluoro（chloro）arenes
3.4 Metal free C N bond formation of alkyl substituted arenes
3.5 Conclusion
References
4 Direct Coupling of Azole C-H Bonds with Nitrogen Groups
4.1 Introduction
4.2 Copper catalyzed/mediated amination
4.3 Acid promoted amination
4.4 Metal free amination
4.5 Conclusion
References
5 Copper-Promoted Direct sp2C-H Bond Transformation
5.1 Introduction
5.2 Aromatic ring C H bond functionalization
5.2.1 Cyclization C H bond functionalization
5.2.2 Non cyclization C H bond functionalization
5.3 Heteroaromatic C H bond functionalization
5.3.1 Arylation of heteroaromatic C H bonds
5.3.2 Alkenylation of oxazoles with bromoalkenes
5.3.3 Amination of heteroaromatic C H bonds
5.4 Conclusion
References
6 lron Catalysis for Hydrosilyaltion
6.1 Introduction
6.2 Hydrosilylation of olefins
6.3 Hydrosilylation of aldehydes and ketones
6.4 Hydrosilylation reduction of amides to amines
6.5 Conclusion
References
7 Stereoselective Formation Chiral Heterocyclic Compounds via Cross Dehydrogenative Coupling Reactions of sp3C-H Bonds
7.1 Introduction
7.2 Copper catalyzed synthesis of tetrahydroisoquinoline derivatives
7.3 Organocatalytic synthesis of xanthene and indole derivatives
7.4 Copper catalyzed synthesis of indole derivatives
7.5 Conclusion
References
8 Synthesis of Cyclpentadienyl Titanium or Zirconium Complexes and Application in Hydrogenation of Olefins
8.1 Synthesis of cyclopentadienyl zirconium complexes
8.2 Synthesis of cyclopentadienyl titanium complexes
8.3 Hydrogenation of olefins using titanocenes
References
1.1 Introduction
1.2 Construction of carbazoles
1.2.1 Tandem C H functionalization and C N bond formation
1.2.2 Pd （OAc）2 catalyzed oxidative biaryl synthesis
1.3 Construction of benzoxazoles
1.4 Construction of benzimidazoles
1.5 Construction of 2 substituted benzothiazoles
1.6 Construction of 3 aryl/alkylindazoles
1.7 Construction of indoles
1.8 Construction of indole derivatives oxindoles and indolines
1.8.1 Construction of oxindoles
1.8.2 Construction of indolines
1.9 Construction of benzolactams and phthalimides
1.10 Construction of dibenzofurans
1.11 Construction of brigehead unsaturated bicyclic enamines
1.12 Conclusion
References
2 Heterocycle Synthesis through Direct Coupling of Saturated C-H Bonds
2.1 Introduction
2.2 Intramolecular cyclization
2.2.1 C C bond formation
2.2.2 C N bond formation
2.2.3 C O bond formation
2.3 Intermolecular cyclization
2.3.1 Cyclization with insertion of alkenes
2.3.2 Cyclization with insertion of CO
2.3.3 Cyclization with insertion of alkynes
2.4 Conclusions
References
3 Direct Coupling of Aromatic C-H Bonds with a Nitrogen Atom
3.1 Introduction
3.2 C N bond formation of arenes having directing groups
3.2.1 Copper catalyzed/mediated C N bond formation
3.2.2 Palladium catalyzed C N bond formation
3.3 Copper（Ⅱ） acetate catalyzed/mediated C N bond formation of polyfluoro（chloro）arenes
3.4 Metal free C N bond formation of alkyl substituted arenes
3.5 Conclusion
References
4 Direct Coupling of Azole C-H Bonds with Nitrogen Groups
4.1 Introduction
4.2 Copper catalyzed/mediated amination
4.3 Acid promoted amination
4.4 Metal free amination
4.5 Conclusion
References
5 Copper-Promoted Direct sp2C-H Bond Transformation
5.1 Introduction
5.2 Aromatic ring C H bond functionalization
5.2.1 Cyclization C H bond functionalization
5.2.2 Non cyclization C H bond functionalization
5.3 Heteroaromatic C H bond functionalization
5.3.1 Arylation of heteroaromatic C H bonds
5.3.2 Alkenylation of oxazoles with bromoalkenes
5.3.3 Amination of heteroaromatic C H bonds
5.4 Conclusion
References
6 lron Catalysis for Hydrosilyaltion
6.1 Introduction
6.2 Hydrosilylation of olefins
6.3 Hydrosilylation of aldehydes and ketones
6.4 Hydrosilylation reduction of amides to amines
6.5 Conclusion
References
7 Stereoselective Formation Chiral Heterocyclic Compounds via Cross Dehydrogenative Coupling Reactions of sp3C-H Bonds
7.1 Introduction
7.2 Copper catalyzed synthesis of tetrahydroisoquinoline derivatives
7.3 Organocatalytic synthesis of xanthene and indole derivatives
7.4 Copper catalyzed synthesis of indole derivatives
7.5 Conclusion
References
8 Synthesis of Cyclpentadienyl Titanium or Zirconium Complexes and Application in Hydrogenation of Olefins
8.1 Synthesis of cyclopentadienyl zirconium complexes
8.2 Synthesis of cyclopentadienyl titanium complexes
8.3 Hydrogenation of olefins using titanocenes
References
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